Equation Rif5 intermediate 2 + 2 reduced ferredoxin [iron-sulfur] cluster + dioxygen + 2 H+ → Rif5 intermediate 3 + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
Enzymes and Genes
Sub-reaction of 1.14.15.-: 34α-deoxy-rifamycin W + 10 reduced ferredoxin [iron-sulfur] cluster + 5 dioxygen + 10 H+ → 25-O-deacetyl-27-O-demethylrifamycin S + CO2 + 10 oxidized ferredoxin [iron-sulfur] cluster + 7 H2O